Aqua{6,6′-dimethoxy-2,2′-[propane-1,3-diylbis(nitrilomethylidyne)]diphenolato}copper(II)
نویسنده
چکیده
In the asymmetric unit of the title compound, [Cu(C(19)H(20)N(2)O(4))(H(2)O)], there are two independent mononuclear Cu(II) complexes. The coordination environment of each Cu(II) ion is square-pyramidal completed by two N atoms and two O atoms forming the basal plane, and one O atom of the water mol-ecule occupying the apical position. Neighbouring complexes are connected via O-H⋯O hydrogen bonds between the water mol-ecule and the meth-oxy group, forming a chain structure along the a axis. The propyl-ene groups of the two independent complexes are disordered over two positions with site occupancies of 0.361 (7):0.639 (7) and 0.224 (8):0.776 (8). The crystal under investigation was a partial inversion twin.
منابع مشابه
Dichlorido-2κ2 Cl-{μ-6,6′-dimethoxy-2,2′-[propane-1,3-diylbis(nitrilomethylidyne)]diphenolato-1κ4 O 1,N,N′,O 1′:2κ2 O 1,O 1′}copper(II)zinc(II)
In the title compound, [CuZnCl(2)(C(19)H(20)N(2)O(4))], the Cu(II) ion exhibits a slightly distorted square-planar coordination geometry defined by two N atoms and two O atoms of the 6,6'-dimeth-oxy-2,2'-[propane-1,3-diylbis(nitrilo-methyl-idyne)]diphenolate Schiff base ligand. The Zn(II) ion is also four-coordinated by the two phenolate O atoms of the Schiff base ligand and by two cis-coordina...
متن کامل{μ-6,6′-Dimethoxy-2,2′-[propane-1,3-diylbis(nitrilomethylidyne)]diphenolato}trinitratocopper(II)europium(III)
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متن کاملAqua{6,6-dimethoxy-2,2′-[propane-1,3-diylbis(nitrilomethylidyne)]diphenolato-κ4 O,N,N′,O′}copper(II) acetonitrile solvate
In the title compound, [Cu(C(19)H(20)N(2)O(4))(H(2)O)]·C(2)H(3)N, the Cu(II) ion is coordinated by two N and two O atoms from the tetra-dentate Schiff base ligand, which contains a propyl-ene fragment disordered over two conformations in a 0.64 (1):0.36 (1) ratio, and one O atom from the water mol-ecule in a distorted square-pyramidal geometry. In the crystal structure, inter-molecular O-H⋯O hy...
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متن کامل{μ-6,6′-Dimethoxy-2,2′-[propane-1,3-diylbis(nitrilomethylidyne)]diphenolato}dimethanoltrinitratonickel(II)europium(III) methanol disolvate
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عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2009